Determining the kinetics of discrete aqueous redox reaction sub-steps using computational methods: Application to reactions of plutonyl (PuO2+/2+) with Fe2+, Fe3+, and hydroxyl radical (•OH)

Will M. Bender; Udo Becker

doi:10.2475/09.2018.02

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Determining the kinetics of discrete aqueous redox reaction sub-steps using computational methods: Application to reactions of plutonyl (PuO₂^+/2+) with Fe²⁺, Fe³⁺, and hydroxyl radical (•OH)

Will M. Bender and Udo Becker

American Journal of Science November 2018, 318 (9) 893-920; DOI: https://doi.org/10.2475/09.2018.02

Will M. Bender

Department of Earth and Environmental Sciences, University of Michigan, Room 2534, 1100 North University Avenue, Ann Arbor, Michigan 48109-1005

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For correspondence: benderwm@umich.edu ubecker@umich.edu

Udo Becker

Department of Earth and Environmental Sciences, University of Michigan, Room 2534, 1100 North University Avenue, Ann Arbor, Michigan 48109-1005

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For correspondence: benderwm@umich.edu ubecker@umich.edu

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American Journal of Science

Vol. 318, Issue 9

1 Nov 2018

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Determining the kinetics of discrete aqueous redox reaction sub-steps using computational methods: Application to reactions of plutonyl (PuO₂^+/2+) with Fe²⁺, Fe³⁺, and hydroxyl radical (•OH)

Will M. Bender, Udo Becker

American Journal of Science Nov 2018, 318 (9) 893-920; DOI: 10.2475/09.2018.02