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Research ArticleArticles

A generalized model for predicting the thermodynamic properties of clay minerals

Philippe Blanc, Philippe Vieillard, Hélène Gailhanou, Stéphane Gaboreau, Éric Gaucher, Claire I. Fialips, Benoît Madé and Eric Giffaut
American Journal of Science October 2015, 315 (8) 734-780; DOI: https://doi.org/10.2475/08.2015.02
Philippe Blanc
* BRGM, 3 Avenue C. Guillemin, BP6009, F-45060 Orleans, France
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  • For correspondence: p.blanc@brgm.fr
Philippe Vieillard
** CNRS-IC2MP-UMR-7285 -Hydrasa, 5 Avenue Albert Turpain, 86022 POITIERS-Cedex, France
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Hélène Gailhanou
* BRGM, 3 Avenue C. Guillemin, BP6009, F-45060 Orleans, France
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Stéphane Gaboreau
* BRGM, 3 Avenue C. Guillemin, BP6009, F-45060 Orleans, France
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Éric Gaucher
* BRGM, 3 Avenue C. Guillemin, BP6009, F-45060 Orleans, France
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Claire I. Fialips
§ Andra, F-92298 Châtenay-Malabry Cedex, France.
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Benoît Madé
§ Andra, F-92298 Châtenay-Malabry Cedex, France.
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Eric Giffaut
§ Andra, F-92298 Châtenay-Malabry Cedex, France.
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American Journal of Science: 315 (8)
American Journal of Science
Vol. 315, Issue 8
1 Oct 2015
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A generalized model for predicting the thermodynamic properties of clay minerals
Philippe Blanc, Philippe Vieillard, Hélène Gailhanou, Stéphane Gaboreau, Éric Gaucher, Claire I. Fialips, Benoît Madé, Eric Giffaut
American Journal of Science Oct 2015, 315 (8) 734-780; DOI: 10.2475/08.2015.02

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A generalized model for predicting the thermodynamic properties of clay minerals
Philippe Blanc, Philippe Vieillard, Hélène Gailhanou, Stéphane Gaboreau, Éric Gaucher, Claire I. Fialips, Benoît Madé, Eric Giffaut
American Journal of Science Oct 2015, 315 (8) 734-780; DOI: 10.2475/08.2015.02
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  • Article
    • Abstract
    • INTRODUCTION
    • PRELIMINARY CONSIDERATIONS
    • MODEL FOR PREDICTING THE ENTHALPY OF FORMATION OF CLAY MINERALS
    • THE POLYHEDRAL DECOMPOSITION MODEL
    • EXTRAPOLATING CAPACITIES
    • UNCERTAINTY ISSUES
    • COMBINING THE PREDICTIVE MODELS: GIBBS FREE ENERGY ESTIMATES
    • CONCLUSIONS
    • ACKNOWLEDGMENTS
    • APPENDIX 1
    • APPENDIX 2
    • REFERENCES
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Keywords

  • clay mineral
  • thermodynamic data
  • enthalpy
  • Gibbs free energy
  • entropy
  • phyllosilicates
  • chlorite

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