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American Journal of Science, Vol. 301, October 2001, P.727-752; doi:10.2475/ajs.301.8.727

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Spatial Patterns Of Diagenesis during Geothermal Circulation in Carbonate Platforms

Alicia M. Wilson*, Ward Sanford**, Fiona Whitaker*** and Peter Smart****

* U.S. Geological Survey, Reston, Virginia, 20192; now at Department of Geological Sciences, University of South Carolina, Columbia, South Carolina 29208
** U.S. Geological Survey, MS 431, Reston, Virginia 20192
*** Department of Earth Sciences, University of Bristol, Bristol BS8 1RJ, United Kingdom
**** School of Geographical Sciences, University of Bristol, Bristol BS8 1SS, United Kingdom

Geothermal convection of seawater deep in carbonate platforms could provide the necessary supply of magnesium for dolomitization at temperatures high enough to overcome kinetic limitations. We used reactive-transport simulations to predict the rates and spatial patterns of dolomitization during geothermal convection in a platform that was 40 km across and 2 km thick. In the simulations, porosity and permeability decrease with depth to account for sediment compaction.

Dolomitization of a platform consisting of medium grained (~0.05 mm) sediments occurred in a broad band ranging from ~2.5 km depth near the margin to ~1.5 km depth near the platform center. The area of dolomitization is deep enough that temperatures exceed ~50°C but not so deep that low permeabilities restrict mass transport. Complete dolomitization in the center of this zone is estimated to require at least 60 my. Incorporation of permeability contrasts, permeable beds, and reactive beds focused dolomitization strongly and reduced the estimated time required for dolomitization by as much as 50 percent. Dolomitization created magnesium-depleted, calcium-rich fluids in less than 10 ky, and results support a link between dolomitization and anhydrite precipitation where adequate sulfate is available.




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